Gallery

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B. F. Abrahams, M. G. Haywood, and R. Robson, ‘Cu(SO3)47-: A Readily Accessible Building Block for New Coordination Polymers’, Crystal Growth & Design, 8 (2008), 1288-93.

CuSO34Fe3Otest Fig4f


 

B. F. Abrahams, C. T. Abrahams, M. G. Haywood, T. A. Hudson, B. Moubaraki, K. S. Murray, and R. Robson, ‘3D-Metal Derivatives of the [CuI(SO3)4]7- Ion: Structure and Magnetism’, Dalton Transactions, 41 (2012), 4091-99.

Fig-5SO3 Fig-5SO3BS


 

B. F. Abrahams, T. A. Hudson, L. J. McCormick, and R. Robson, ‘Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)-a Topology’, Crystal Growth & Design, 11 (2011), 2717-20.

NBu42Ni2dhbq3SF


 

B. F. Abrahams, N. J. FitzGerald, and R. Robson, ‘An Extensive Class of Solids Full of Holes Large Enough to Enclose over 200 Molecules of H2O’, Angewandte Chemie-International Edition, 46 (2007), 8640-43.

figure-2c


 

B. F. Abrahams, P. A. Jackson, and R. Robson, ‘A Robust (10,3)-a Network Containing Chiral Micropores in the Ag-Coordination Polymer of a Bridging Ligand That Provides Three Bidentate Metal-Binding Sites’, Angewandte Chemie-International Edition, 37 (1998), 2656-59.

AgHAT_packing27_helix_cropped_brighter AgHAT_segment7_2x10_circuits_cropped_brighter


 

B. F. Abrahams, B. F. Hoskins, R. Robson, and D. A. Slizys, ‘a-Polonium Coordination Networks Constructed from Bis(Imidazole) Ligands’, CrystEngComm (2002), 478-82.

a-Pol-Fig5b


 

B. F. Abrahams, M. G. Haywood, and R. Robson, ‘Guanidinium Ion as a Symmetrical Template in the Formation of Cubic Hydrogen-Bonded Borate Networks with the Boracite Topology’, Journal of the American Chemical Society, 127 (2005), 816-17.

grnfig3a


 

B. Moubaraki, K. S. Murray, T. A. Hudson, and R. Robson, ‘Tetranuclear and Octanuclear Cobalt(II) Citrate Cluster Single Molecule Magnets’, European Journal of Inorganic Chemistry(2008), 4525-29.

citratecubane_singlecubane3_cropped_brighter


 

B. F. Abrahams, N. J. FitzGerald, T. A. Hudson, R. Robson, and T. Waters, ‘Closed and Open Clamlike Structures Formed by Hydrogen-Bonded Pairs of Cyclotricatechylene Anions That Contain Cationic “Meat” ‘, Angewandte Chemie-International Edition, 48 (2009), 3129-32.

CTCclam_fig13A_cropped_brighter_forweb CTCclam_fig14_brighter_cropped_forweb figure4


 

B. F. Abrahams, N. J. Fitzgerald, and R. Robson, ‘Cages with Tetrahedron-Like Topology Formed from the Combination of Cyclotricatechylene Ligands with Metal Cations’, Angewandte Chemie-International Edition, 49 (2010), 2896-99.

VO6ctc4Cs4


 

B. F. Abrahams, H. Maynard-Casely, R. Robson and K. F. White, ‘Copper(II) coordination polymers of imdc (H2imdc+ = the 1,3-bis(carboxymethyl)imidazolium cation): Unusual sheet interpenetration and an unexpected single crystal-to-single crystal  transformation.’CrystEngComm 15 (2013),9729-9737.

Cuimdcimagae


 

B. F. Abrahams, B. A. Boughton, N. J. FitzGerald, J. L. Holmes, and R. Robson, ‘A Highly Symmetric Diamond-Like Assembly of Cyclotricatechylene-Based Tetrahedral Cages’, Chemical Communications, 47 (2011), 7404-06.

CTCtet_fig4_cropped_brighter_forweb CTCTetrahedron2_Fig11_cropped_adjusted_forweb TOC-graphic


 

B. F. Abrahams, L. J. McCormick, B. Moubaraki, K. S. Murray, R. Robson, and T. Waters, ‘Two Cu-21 Clusters with Pseudo-D3 Symmetry Derived from the D-Saccharate Pentaanion, C6H5O85-‘, Chemistry- A European Journal, 17 (2011), 7454-59.

cubicbfaTOC lm106orthoSF2


 

R. J. Holmes, B. F. Abrahams, V. Murray, W. A. Denny, and W. D. McFadyen, ‘A 2D Hydrogen-Bonded Network Constructed from Large Organic Dications’, Journal of Molecular Structure,975 (2010), 186-89.

Fig-2a


 

B. F. Abrahams, B. F. Hoskins, and R. Robson, ‘A Honeycomb Form of Cadmium Cyanide – a New Type of 3-D Arrangement of Interconnected Rods Generating Infinite Linear Channels of Large Hexagonal Cross-Section’, Journal of the Chemical Society-Chemical Communications(1990), 60-61.

CdCNtbutOH_packing8_cropped_brighter_forweb


 

B. F. Abrahams, A. Hawley, M. G. Haywood, T. A. Hudson, R. Robson, and D. A. Slizys, ‘Serendipity and Design in the Generation of New Coordination Polymers: An Extensive Series of Highly Symmetrical Guanidinium-Templated, Carbonate-Based Networks with the Sodalite Topology’, Journal of the American Chemical Society, 126 (2004), 2894-2904.

Fig6b2 Fig6a3 Nixtal


 

B. F. Abrahams, J. Coleiro, B. F. Hoskins, and R. Robson, ‘Gas Hydrate-Like Pentagonal Dodecahedral M2(H2O)18 Cages (M = Lanthanide or Y) in 2,5-Dihydroxybenzoquinone-Derived Coordination Polymers’, Chemical Communications (1996), 603-04.

ce2dhbq32010 fig-51


 

B. F. Abrahams, N. J. FitzGerald, and R. Robson, ‘A Doughnut-Like (MnIII12 Metallocycle Formed by a Rigid Angular Bis-Catecholate with a Nanometer-Sized Central Hole’, Inorganic Chemistry,49 (2010), 5953-56.

fig-5 TOCpict


 

B. F. Abrahams, R. W. Elliott, T. A. Hudson and R. Robson, PtS-Related {[CuI(F4TCNQII-)]}Networks, Crystal Growth & Design, 13 (2013), 3018-3027.

TOCCGDnew1


 

B. F. Abrahams, M. J. Grannas, T. A. Hudson, S. A. Hughes, N. H. Pranoto, and R. Robson, ‘Synthesis, Structure and Host-Guest Properties of (Et4N)2(SnIVCaII(chloranilate)4 , a New Type of Robust Microporous Coordination Polymer with a 2D Square Grid Structure’, Dalton Transactions, 40 (2011), 12242-47.

SnCaCS2S2TOCspec1


 

B. F. Abrahams, D. J. Price, and R. Robson, ‘Tetraanionic Organoborate Squares Glued Together by Cations to Generate Nanotubular Stacks’, Angewandte Chemie-International Edition, 45 (2006), 806-10.

DP421Mbenzylsq JACSTOC spirocover


 

B. F. Abrahams, R. W. Elliott, T. A. Hudson, and R. Robson, ‘A New Class of Easily Generated TCNQ2--Based Coordination Polymers’, Crystal Growth & Design, 10 (2010), 2860-62.

Fig-2 TCNQphenylpyr


 

B. F. Abrahams, B. A. Boughton, H. Choy, O. Clarke, M. J. Grannas, D. J. Price, and R. Robson, ‘Trianionic Organoborate Triangles’, Inorganic Chemistry, 47 (2008), 9797-803.

Fig5b imHB3L3_singlecat


 

B. F. Abrahams, M. Moylan, S. D. Orchard, and R. Robson, ‘Zinc Saccharate: A Robust, 3d Coordination Network with Two Types of Isolated, Parallel Channels, One Hydrophilic and the Other Hydrophobic’, Angewandte Chemie-International Edition, 42 (2003), 1848-51.

znsaccnew


 

B. F. Abrahams, R. W. Elliott, T. A. Hudson, and R. Robson, ‘A New Type of 3D [MII2(tcnq-II)3]2-Coordination Network with Spacious Channels of Hexagonal Cross-Section Generated from tcnqH2‘, CrystEngComm, 14 (2012), 351-54.

AltFig3a